| Data | Casa | Visitante | Resultado |
|---|---|---|---|
| 16/05/14 16:00 | FC Málaga | UD Levante | 1:0 |
| 17/05/14 11:00 | Real Madrid | Espanyol Barcelona | 3:1 |
| 17/05/14 13:00 | FC Barcelona | Atlético Madrid | 1:1 |
| 17/05/14 17:00 | FC Valencia | Celta Vigo | 2:1 |
| 18/05/14 07:00 | Real Sociedad | FC Villarreal | 1:2 |
| 18/05/14 13:00 | Real Valladolid | FC Granada | 0:1 |
| 18/05/14 13:00 | CA Osasuna | Real Betis Sevilla | 2:1 |
| 18/05/14 13:00 | UD Almeria | Athletic Bilbao | 0:0 |
| 18/05/14 13:00 | Rayo Vallecano | FC Getafe | 1:2 |
| 18/05/14 16:00 | FC Sevilla | FC Elche | 3:1 |